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Nanoparticles
(NPs) are known to exhibit properties which are very distinct from
bulk micro- or macroscopic materials and which may be ideal in different
aspects. NPs fall into different classes like spheroids, toroids,
rods, and tubes. These basic forms may set up a toolbox for designed
functional structures on the nanoscale. A prerequisite for achieving
such functional nanomaterials is the synthesis of well defined (monodisperse)
NPs. These have already been shown to exhibit extraordinary properties
for advanced applications in electronics, sensing, catalysis, storage
devices and for low dimensional materials.
Research is focused on novel carbon and transition metal oxide NPs,
such as
vanadium oxide nanotubes, TiO2, MoO3, and WO3
nanorods, on the development of cheap, air-stable precursors, as well
as on effective syntheses, and scale-up procedures.
Characterization
of structure and morphology is based on electron
microscopy, X-ray diffraction,
vibrational and optical spectroscopy, as well as solid state NMR.
Physical properties are investigated by chemical, thermal, electrochemical,
conductivity, magnetic, and zeta-potential measurements.
News:
Electron microscopy
Visit our new electron microscopy site: http://www.microscopy.ethz.ch
Author: Dr. Frank Krumeich
May 6, 2004
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See
the MoO3 nanorods - move the slider:
(QuickTime
plug-in needed)
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© 2002, ETH Zurich and the Authors
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| Review:
Greta
R. Patzke, Frank Krumeich, Reinhard Nesper,
Nanoröhren und Nanostäbe auf Oxidbasis - anisotrope Bausteine
für künftige Nanotechnologien
Angew.
Chem. 2002, 114, 2554-2571
Oxidic
Nanotubes and Nanorods - Anisotropic Modules for a Future Nanotechnology
Angew.
Chem. Int. Ed. 2002, 41, 2446-2461
Recent
publications:
J.
Zygmunt, F. Krumeich, R. Nesper
Novel Silica Nanotubes with a High Aspect
Ratio – Synthesis and Structural Characterisation
Adv. Mater. 15, 2003, 1538-1541
G.
R. Patzke, F. Krumeich, R. Nesper
Nanoscale Design Strategies: Oxidic Nanorods
Z. Anorg. Allg. Chem. 2002, 628, 2152
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| Collaborations:
Institutional
Collaborations:
ETHZ
(Profs. Gauckler,
Luisi, Spencer)
EPFL (Prof. Forró)
Clemson University (Prof. Carroll)
Max-Planck-Institute
for Solid State Research (Dr. Roth,
)
Max-Planck-Institute
for Chemical Physics (Prof. Kniep, Prof. Grin)
University of Essen (Prof. Schmid)
Industry
Collaborations:
SusTech (Darmstadt, D) www.sustech.de
Henkel (Düsseldorf, D)
ABB (Baden, CH) www.abb.ch
Ivoclar (Schaan, Fl) www.ivoclar.com
Zumtobel (Dornbirn, Au)
Funding:
ETH
Jubiläumsfonds (TEMA, ended 1999)
Swiss
National Research Programm NFP47:
"Supramolecular Functional Materials"
www.nfp47.ch
President: Prof. Andreas Ludi
National
Centre of Competence in Research NCCR:
"Materials with Novel Electronic Properties"
http://www.manep.ch/
Director: Prof. Øystein Fischer
MaNEP
- newsletter
"Nano
Cage Materials"
IHP - European - Network
Coordinator: Prof. Laars Kloo
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